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Specialty Chemicals - Chevron Phillips Chemical Company LLC
 
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Catalyst Presulfiding & Refinery Spiking

CPChem Specialty Chemicals - Catalyst Sulfiding & Pyrolysis Furnace Additive Applications Sulfur chemicals are used to passivate steam cracker furnace walls. In steam cracking, a feedstock such as naphtha or LPG (liquefied petroleum gas) is mixed with steam and passed into a high-temperature furnace. This causes breakdown to ethylene and propylene, the building blocks of the chemical industry. If the furnace walls are not protected or passivated by injecting the feed with sulfur, coking results, severely reducing the effective run life of the furnace.

Organosulfur chemicals are the preferred reagents for catalyst sulfidation. These compounds improve initial catalyst activity and lengthen production cycles for NiMo, CoMo, NiW, and CoW hydrotreating catalysts.  Proper presulfiding allows unit operation at lower temperatures and extends catalyst cycles. Improved catalyst activity can be exploited to increase capacity or to enhance product quality. Organosulfur chemicals may also be used to moderate catalyst activity via low-concentration introduction into the unit's feedstock. This allows for the moderation of initial high catalyst activity and deactivation caused by coking.  Please see our general sulfiding conditions page for more information on this process.

Common agents for these applications include:

We also offer CCA 500, a coke-controlling additive that was developed to improve the economics of ethylene furnace operations. This ethylene furnace additive has been shown to reduce coking rates by up to 90% while also reducing carbon monoxide production from furnaces.