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Normal Alpha Olefins - Chevron Phillips Chemical Company
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Plasticizer Alcohols

C8 through C10 normal alpha olefins are used to produce primary C9 through C11 plasticizer alcohols via hydroformylation or oxo chemistries. The phthalate plasticizers produced from these alcohols gave superior properties to those made from 2-ethyl 1-hexanol. The same chemistry is used to produce C13 to C15 synthetic detergent alcohols from C12 and C14 normal alpha olefins.

Alkenyl Succinic Anhydrides

Alkenyl succinic anhydrides (ASAs) are prepared by heating normal alpha olefins and maleic anhydride to approximately 200°C. Some ASAs are used as dispersants in lube oils and automatic transmission fluids, and as pour-point depressants in lube and crude oils. Others are converted to acid amides, half esters, and diesters. One of the largest applications for ASA is as the paper sizing agent in alkaline media. For this use, normal alpha olefins C16 or C18 are isomerized to a thermodynamic distribution of internal olefins, which are then reacted with maleic anhydride to produce the desired liquid ASA.

Polyvinylchloride Lubricants & Stabilizers

Heat and pressure are applied during the extrusion of polyvinylchloride (PVC) as it moves through the die. Lubricants (waxes) are compounded into the PVC to ensure proper lubrication in the extruder and to control fusion of the PVC compound. Normal alpha olefin C30+ is the preferred lubricant for this application.

During the extrusion process, PVC often begins to decompose. Various materials are used to retard this degradation, including dibutyl or dioctyl tin oxides and/or dioctyl tin mercaptides. These compounds are made using tin (IV) chloride and the corresponding aluminum alkyls, which in turn are derived from normal alpha olefins. The mercaptans used to make the tin mercaptides are usually made from normal alpha olefins.

  PVC Lubricants
Products MSDS TDS Specification Application
Alpha Olefin C24-28 Epoxides, di-/poly- halides, candles, pour point depressants, personal care
Alpha Olefin C26-28 Candles, pour point depressants, lube oil additives, epoxides, alkyl silanes, personal care
Alpha Olefin C30+ PVC lubricants, candles, alkyl silanes, personal care
Alpha Olefin C30+HA Personal care, PVC lubricants, ASA, alkyl silanes
  Plasticizer Alcohols
Products MSDS TDS Specification Application
1-Hexene (C6H12) Polyethylene comonomers, homo-/co- polymers, alkyl aromatics, polyol esters, plasticizer alochols, epoxides, alkyl silanes, metal alkyls, flavors and fragrances
1-Octene (C8H16) Polyethylene comonomers, detergent alcohols, polyalphaolefins, alkyl aromatics, polyol esters, plasticizer alochols, ASA, mercaptans, epoxides, alkyl silanes, personal care, flavors and fragrances
1-Decene (C10H20) Detergent alcohols, polyalphaolefins, alkyl aromatics, plasticizer alcohols, epoxides, di-/poly- halides, personal care, flavors and fragrances
  ASA
Products MSDS TDS Specification Application
1-Octene (C8H16) Polyethylene comonomers, detergent alcohols, polyalphaolefins, alkyl aromatics, polyol esters, plasticizer alochols, ASA, mercaptans, epoxides, alkyl silanes, personal care, flavors and fragrances
1-Dodecene (C12H24) Detergents, plasticizer alcohols, polyalphaolefins, alkyl aromatics, ADMA, ASA, epoxides, mercaptans, di-/poly- halides, alkyl silanes, personal care, flavors and fragrances
1-Tetradecene (C14H28) Maleic anhydride copolymers, AOS, alkyl aromatics, ADMA, detergent alcohols, ASA, epoxides, metal working fluids, di-/poly- halides, alkyl silanes, personal care, flavors and fragrances
1-Hexadecene (C16H32) Maleic anhydride copolymers, AOS, alkyl aromatics, ADMA, ASA, lube oil additives, epoxides, metal working fluids, di-/poly- halides, alkyl silanes, personal care, flavors and fragrances
1-Octadecene (C18H36) Maleic anhydride copolymers, AOS, alkyl aromatics, ADMA, ASA, lube oil additives, epoxides, metal working fluids, di-/poly- halides, alkyl silanes, personal care, flavors and fragrances
Alpha Olefin C26-28 Candles, pour point depressants, lube oil additives, epoxides, alkyl silanes, personal care
Alpha Olefin C30+HA Personal care, PVC lubricants, ASA, alkyl silanes
Isomerized Alpha Olefin C16 Drilling fluids, ASA
Isomerized Alpha Olefin C18 Drilling fluids, ASA
Isomerized Alpha Olefin C16-18 (65:35) Drilling fluids, ASA